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Thermodynamics II:
The following are sample non multiple choice questions
taken from recent exams:
These particular questions cover:
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Qualitative Ideas:
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The Gibbs-Helmholtz Equation: DG=DH
-TDS
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DH0, DS0,
DG0:
Chemical reactions and Phase Changes
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Thermodynamic problem solving
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1 DS0rxn
for the combustion of ethane, a component of natural gas, is 46.4 (J/mol
K). Calculate the absolute entropy for ethane gas.
C2H6(g) + 7/2 O2(g)
®
2 CO2(g) + 3 H2O(g)
(Use the appendix at the back of your book for
any thermodynamic values you may need.)
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Question 2 concerns the following N2O4/
NO2 equilibrium system:
N2O4(g) «
2 NO2(g) DH°
= 57.2 kJ/mol
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2 The
equlibrium constant for this reaction is 5.9 x 10–3 at 298 K.
DGo
for this reaction is ________ kJ/mol .
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